Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide → 2-Di(1'-methylpropyl)phosphinomethyl-2'-methyl-1,1'-binaphthyl
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide | HCID 18929278 | — |
| 반응물 | Aluminium lithium hydride | HCID 21226445 | — |
| 용매 | O-Xylene | HCID 7237 | — |
| 생성물 | 2-Di(1'-methylpropyl)phosphinomethyl-2'-methyl-1,1'-binaphthyl | HCID 19690364 | — |
반응 단계
4 g (7.9 mmol) of 4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide are suspended in 70 ml of absolute xylene and reacted with 400 mg (10.5 mmol) of lithium aluminum hydride using a method analogous to Example 5.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05728886 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-9144b195488a484e95660584bc9d7fc6 |
| 출처 메모 | uspto-grants-1998_03 |