Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Methylpyridine-2-carboxaldehyde → Bis-(3-methyl-pyridin-2-ylmethyl)-amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Methylpyridine-2-carboxaldehyde | HCID 1501874 | — |
| 반응물 | (3-Methylpyridin-2-yl)methanamine | HCID 1514370 | — |
| 반응물 | Sodium triacetoxyborohydride | HCID 5049666 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Bis-(3-methyl-pyridin-2-ylmethyl)-amine | HCID 45098010 | — |
반응 단계
Using General Procedure B: Reaction of 3-methyl-2-aminomethylpyridine and 3-methyl-2-pyridinecarboxaldehyde in CH2Cl2 with NaBH(OAc)3 gave bis-(3-methyl-pyridin-2-ylmethyl)-amine as a yellow oil. 1H NMR (CDCl3) δ 2.33 s, 6H), 4.06 (s, 4H), 7.08 (dd, 2H, J=9, 6 Hz), 7.42 (dd, 2H, J=9, 3 Hz), 8.41 (d, 2H, J=3 Hz).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07863293B2 |
| 출처 데이터셋 | uspto-grants-2011_01 |
| ORD ID | ord-3c63327a6cd144c2a461ba8a471ee995 |
| 출처 메모 | uspto-grants-2011_01 |