Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → 1-Adamantyl 3,4-dichlorophenylthiomethyl ketone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 3,4-Dichlorobenzenethiol | HCID 79964 | — |
| 반응물 | Bromomethyl tricyclo[3.3.1.13,7]dec-1-yl ketone | HCID 197820 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | 1-Adamantyl 3,4-dichlorophenylthiomethyl ketone | HCID 21424044 | — |
반응 단계
1-adamantyl bromomethyl ketone (1.3 g.), 1.1 g. of 3,4-dichlorothiophenol and 800 mg. of anhydrous potassium carbonate in 30 ml. of acetone are stirred at reflux overnight. The solvent is then removed and 60 ml. of water is added to the reaction mixture. The product is filtered off, washed with water and recrystallized from methanol to yield 1-adamantyl 3,4-dichlorophenylthiomethyl ketone, M.P. 105°-110.5° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04036975 |
| 출처 데이터셋 | uspto-grants-1977_07 |
| ORD ID | ord-5fa6384611b3406fa60c6e11270986ca |
| 출처 메모 | uspto-grants-1977_07 |