Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,5-Hexadiene → HCID 22401791, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,5-Hexadiene | HCID 11598 | — |
| 반응물 | 3-(Ethylphenyl)-1,1-dichloro-1-silabutane | HCID 14972032 | — |
| 촉매 | Chloroplatinic acid | HCID 61859 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | HCID 22401791 | HCID 22401791 | 69.9% |
반응 단계
In the same apparatus and procedures as EXAMPLE 1, 37.5 g (0.153 mole) of 3-(ethylphenyl)-1,1-dichloro-1-silabutane and 100 μl of 1% chloroplatinic acid solution in isopropanol were placed and then 5 g (0.061 mole) of 1,5-hexadiene was added dropwise for 5 min. The solution was reacted for 14 hours at reflux under the dry nitrogen atmosphere. Vacuum distillation gave 24.6 g (190°-192° C./0.03 mmHg) of bis[{2-(ethylphenyl)propyl}dichlorosilyl]hexane in 69.8% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05527934 |
| 출처 데이터셋 | uspto-grants-1996_06 |
| ORD ID | ord-559e759ffd6d4bc2a937377745952339 |
| 출처 메모 | uspto-grants-1996_06 |