Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cycloheptanone → Cycloheptanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cycloheptanone | HCID 10400 | — |
| 반응물 | Ammonium Acetate | HCID 517165 | — |
| 반응물 | 1-Amino-3,3,5-trimethylcyclohexyl hydroperoxide | HCID 21510183 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | Cycloheptanone | HCID 10400 | — |
| 생성물 | 3,3,5-Trimethylcyclohexanone | HCID 13398 | — |
반응 단계
To a stirred mixture of cycloheptanone (73.2 g.) and ethanol (200 cc.), containing ammonium acetate (6.4 g.) and kept at or below 0°C was added 1-amino-3,3,5-trimethylcyclohexyl hydroperoxide (69.2 g.; 76% pure). After the solid had dissolved (5 hours) the solution was stored at 0°C overnight and the product worked up as in the previous Examples. There were obtained unreacted cycloheptanone, and dihydroisophorone, and fractions (57.5 g.) b.p. 124° - 130°/0.3 mm.Hg., peroxide equivalent 283, perchloric acid equivalent 278 shown by mass spectroscopy to contain the peroxide ##SPC30##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03947406 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-1db132e4bfd949568cf324ed5126df6a |
| 출처 메모 | uspto-grants-1976_03 |