Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzoyl chloride → 4-Hydroxy-3,5-dimethylphenyl benzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzoyl chloride | HCID 7412 | — |
| 반응물 | 2,6-Dimethylhydroquinone | HCID 69560 | — |
| 용매 | Pyridine | HCID 1049 | — |
| 생성물 | 4-Hydroxy-3,5-dimethylphenyl benzoate | HCID 239104 | — |
반응 단계
Using 4.70 g of 2,6-dimethyl-1,4-dihydroxybenzene, 4.0 ml of benzoyl chloride and 100 ml of pyridine, reaction and workup carried out as in Reference Example gave 6.35 g of 4-benzoyloxy-2,6-dimethylphenol as white crystals, m.p. 139.5-141.0° C. Using 6.35 g of the white crystals, 1.26 g of sodium hydride, 4.2 ml of benzyl bromide and 50 ml of DMF, reaction and workup carried out as in Example 12 gave 4.22 g of yellow oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06358515B2 |
| 출처 데이터셋 | uspto-grants-2002_03 |
| ORD ID | ord-123423b244b54f378abe0c94fe49cb13 |
| 출처 메모 | uspto-grants-2002_03 |