Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
p-Toluidine → 6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | p-Toluidine | HCID 7813 | — |
| 반응물 | Cyclohexanone, 2-(hydroxymethylene)- | HCID 101871 | — |
| 생성물 | 6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one | HCID 607984 | — |
반응 단계
6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one was prepared from p-toluidine and 2-(hydroxymethylene)cyclohexanone in a similar manner as described in Example 1 to give a tan solid. 1H-NMR (CDCl3): δ 8.65 (s, 1H), 7.43 (s, 1H), 7.30 (d, 1H), 7.20 (d, 1H), 2.98 (t, 2H), 2.65 (t, 2H), 2.45 (s, 3H), 2.26 (quint, 2H); MS m/z 220 (M+1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07419997B2 |
| 출처 데이터셋 | uspto-grants-2008_09 |
| ORD ID | ord-f91b0975afbb4cafba1a36e6ff16f394 |
| 출처 메모 | uspto-grants-2008_09 |