Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl bromide → 1-Ferrocenyl-I-methyl-1,3-butadiene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl bromide | HCID 7841 | — |
| 반응물 | HCID 178466060 | HCID 178466060 | — |
| 반응물 | HCID 178506586 | HCID 178506586 | — |
| 생성물 | 1-Ferrocenyl-I-methyl-1,3-butadiene | HCID 131722479 | 99% |
반응 단계
According to the step flow described in Example 1, about 274 mg (1.20 mmole) of ferrocenyl methyl ketone react with 242 mg (2.0 mmole) of allyl bromide and 1.77 mmole of samarium diiodide in a temperature range of about 0° C. to room temperature to produce an oil-type 1-Ferrocenyl-1-methyl-1,3-butadiene (3b) with a weight of about 302 mg (1.19 mmole) and a yield of about 99%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06211392B1 |
| 출처 데이터셋 | uspto-grants-2001_04 |
| ORD ID | ord-d2cc93ecc2254f4f940d9c3d542781d0 |
| 출처 메모 | uspto-grants-2001_04 |