Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethylamine → 1-[(4-Methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | 4-(Methylsulfanyl)thiophenol | HCID 136896 | — |
| 반응물 | Propanehydrazonoyl chloride, N-(4-methoxyphenyl)-2-oxo- | HCID 2844936 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 1-[(4-Methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone | HCID 53800153 | — |
반응 단계
A suspension of 31.7 g (0.139 mol)of 1-chloro-1-[(4-methoxyphenyl)hydrazono]-2-propanone in 400 ml of ethanol was treated with 23.4 g of 4-methylthiothiophenol and 23.4 of triethylamine. The suspension was heated at reflux for 2 hours and cooled. The resultant suspension was filtered and the precipitate was washed with 1 portion of cold ethanol. The solids were dried in vacuo to yield 1-[(4-methylthiophenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone, mp 124-127° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06214810B1 |
| 출처 데이터셋 | uspto-grants-2001_04 |
| ORD ID | ord-1a5e2a8ef8344c569c9a42f45a17c50a |
| 출처 메모 | uspto-grants-2001_04 |