Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethyl phenylmalonate → 2-Phenyl-1,3-propanediol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethyl phenylmalonate | HCID 66514 | — |
| 반응물 | Aluminium lithium hydride | HCID 21226445 | — |
| 생성물 | 2-Phenyl-1,3-propanediol | HCID 254178 | — |
반응 단계
Diethyl phenylmalonate is reduced with lithium aluminium hydride to give 2-phenyl-propane-1,3-diol and esterified with an equimolar amount of benzenesulphochloride in anhydrous pyridine to give 2-phenylpropane-1,3-diol monobenzenesulphonate (wax-like substance). Reaction thereof with the potassium salt of hexadecanethiol in ethanol gives the desired 3-hexadecylthio-2-phenylpropan-1-ol (wax-like substance).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04444766 |
| 출처 데이터셋 | uspto-grants-1984_04 |
| ORD ID | ord-7f5d1e8ecac34e5992d55dd88c945cb7 |
| 출처 메모 | uspto-grants-1984_04 |