Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
7-Quinolinemethanol → 7-Quinolinecarboxaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 7-Quinolinemethanol | HCID 97609 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 7-Quinolinecarboxaldehyde | HCID 4712255 | 94.2% |
반응 단계
A mixture of 8.6 parts of 7-quinolinemethanol, 20 parts of manganese(IV)oxide and 130 parts of dichloromethane was stirred for 24 hours at room temperature. The reaction mixture was filtered over diatomaceous earth and the filtrate was evaporated. The residue was purified by column chromatography (silica gel; CH2Cl2 /CH3OH 98:2). The eluent of the desired fraction was evaporated, yielding 8 parts (94.2%) of 7-quinolinecarboxaldehyde; mp. 56° C. (interm. 1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05268380 |
| 출처 데이터셋 | uspto-grants-1993_12 |
| ORD ID | ord-c2909b5dbb8d4e4994c854d8f099dd41 |
| 출처 메모 | uspto-grants-1993_12 |