참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methanol | HCID 887 | — |
| 반응물 | Sodium Chloride | HCID 5234 | — |
| 반응물 | Triphenyltin Chloride | HCID 12540 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Triphenyl tin methoxide | HCID 23451602 | — |
반응 단계
115.5 g of triphenyl tin chloride are dissolved in a mixture of 450 g of absolute methanol and 300 g of absolute tetrahydrofuran and mixed with a solution of 7.02 g of sodium in 150 ml of absolute methanol. After stirring for 2 hours at room temperature the resulting precipitate of sodium chloride is filtered off. The solution of triphenyl tin methoxide obtained is combined, accompanied by stirring, with a solution of 600 g of the epoxy resin modified with diketene described in Example 2 dissolved in 300 g of absolute tetrahydrofuran. After stirring for a further 2 hours at room temperature and after distilling off the solvent 696 g of a reddish brown glassy solid product of formula VI above are obtained. Tin content: calculated 5.51%; found 5.45%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US04016141 |
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| 출처 데이터셋 | uspto-grants-1977_04 |
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| ORD ID | ord-daa566e319864535b88c11e65a57de7e |
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| 출처 메모 | uspto-grants-1977_04 |
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