Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acid → 5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acid | HCID 12398821 | — |
| 반응물 | 2-carboxy-5-oxo-5H-dibenzo[a,d]cycloheptene | HCID 12563001 | — |
| 반응물 | ethyl (5-oxo-5H-dibenzo[a,d]cyclohepten-2yl)acetate | HCID 53675848 | — |
| 생성물 | 5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo- | HCID 173910 | — |
반응 단계
The compounds of Formula I can be prepared by conducting an Arndt-Eistert reaction upon 5-oxo-5H-dibenzo[a,d]-cycloheptene-2-carboxylic acid to afford, in various steps thereof, 5-oxo-5H-dibenzo[a,d]cyclohepten -2-acetic acid ethyl ester and 5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acid. 2-(5-Oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionic acid, and the corresponding esters of the aforementioned acids can be obtained via alkylation and/or esterification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04020094 |
| 출처 데이터셋 | uspto-grants-1977_04 |
| ORD ID | ord-a275555ec09a492aaebc45e7412fac3b |
| 출처 메모 | uspto-grants-1977_04 |