돌아가기
Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 329319생성일: 2026년 10월 24일

5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acid → 5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo-

https://huagongshe.com/ko/reaction/329319

반응식

참여 물질

역할이름HCID투입량
반응물5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acidHCID 12398821—
반응물2-carboxy-5-oxo-5H-dibenzo[a,d]cyclohepteneHCID 12563001—
반응물ethyl (5-oxo-5H-dibenzo[a,d]cyclohepten-2yl)acetateHCID 53675848—
생성물5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo-HCID 173910—

반응 단계

The compounds of Formula I can be prepared by conducting an Arndt-Eistert reaction upon 5-oxo-5H-dibenzo[a,d]-cycloheptene-2-carboxylic acid to afford, in various steps thereof, 5-oxo-5H-dibenzo[a,d]cyclohepten -2-acetic acid ethyl ester and 5-oxo-5H-dibenzo[a,d]cyclohepten-2-acetic acid. 2-(5-Oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionic acid, and the corresponding esters of the aforementioned acids can be obtained via alkylation and/or esterification.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04020094
출처 데이터셋uspto-grants-1977_04
ORD IDord-a275555ec09a492aaebc45e7412fac3b
출처 메모uspto-grants-1977_04