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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 341898생성일: 2026년 10월 24일

4-Chloro-o-xylene → 2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenone

https://huagongshe.com/ko/reaction/341898

반응식

참여 물질

역할이름HCID투입량
반응물4-Chloro-o-xyleneHCID 32886—
반응물Oxalyl chlorideHCID 65578—
반응물4,4'-Carbonyldiphthalic anhydrideHCID 75498—
생성물2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenoneHCID 15027172—

반응 단계

Specific benzophenonetetracarboxylic dianhydrides preferred in this invention are readily available from commercial sources or synthesis. For instance, 3,3',4,4'-benzophenonetetracarboxylic dianhydride (D1) is available from Aldrich Chemical Co., Inc. (1001 W. St. Paul Ave., Milwaukee, Wis. 53233). 2,2'-Dichloro-4,4',5,5'-benzophenone tetracarboxylic dianhydride (D2) is available from 4-chloro-o-xylene by Friedel-Crafts acylation with oxalyl chloride to give 2,2'dichloro-4,4',5,5',-tetramehtylbenzophenone, followed by oxidation with nitric acid and dehydration of the resulting tetracarboxylic acid as described by Falcigno, et al., J. Poly. Sci. 1992, 30, 1433.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05856430
출처 데이터셋uspto-grants-1999_01
ORD IDord-fafc4b42d9da4526b79dcae11ee1a49e
출처 메모uspto-grants-1999_01