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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 35951생성일: 2026년 10월 24일

Triethylamine → 1-(Bromomethyl)-3-[[3-(hexadecyloxy)-2-methoxypropoxy]methyl]benzene

https://huagongshe.com/ko/reaction/35951

반응식

참여 물질

역할이름HCID투입량
반응물TriethylamineHCID 8471—
반응물Methanesulfonyl chlorideHCID 31297—
반응물Lithium BromideHCID 82050—
반응물3-[[3-(Hexadecyloxy)-2-methoxypropoxy]methyl]benzenemethanolHCID 19939554—
용매WaterHCID 962—
용매Diethyl EtherHCID 3283—
용매TetrahydrofuranHCID 8028—
생성물1-(Bromomethyl)-3-[[3-(hexadecyloxy)-2-methoxypropoxy]methyl]benzeneHCID 19939557—

반응 단계

To a solution of 4 g of 3-[[3-(hexadecyloxy)-2methoxypropoxy]methyl]benzenemethanol and 3.05 g of mesyl chloride in 40 ml of tetrahydrofuran at 0° C. was added over 20 minutes a solution of 2.69 g of triethylamine in 10 ml of tetrahydrofuran. A 7.71 g portion of lithium bromide was added and the mixture was stirred at room temperature for 2 hours. The solution was diluted with ether, poured into water, and extracted with ethanol. The extract was washed with saturated sodium bicarbonate solution, dried and evaporated, giving the desired compound as an oil.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05411983
출처 데이터셋uspto-grants-1995_05
ORD IDord-06f21b68240d4771ae184ffc18c3bafd
출처 메모uspto-grants-1995_05