Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,4-Benzenedicarboxylate → Ruthenium isophthalate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,4-Benzenedicarboxylate | HCID 154269 | — |
| 반응물 | 1,3-Benzenedicarboxylic acid, sodium salt (1:2) | HCID 14535627 | — |
| 반응물 | Ruthenium terephthalate | HCID 86746321 | — |
| 생성물 | Ruthenium isophthalate | HCID 86746320 | — |
반응 단계
Ruthenium isophthalate was prepared and tested as described above in the case of ruthenium terephthalate. Elementary analysis indicates Ru(C8H4O4)2Ru; theor. 23.5, found 23.8; C, theor. 44.7, found 45.0; H, theor. 1.85, found 1.90. Thus, as with the terephthalate, reaction of RuCl3 with sodium isophthalate solution in air yields an Ru+4 not Ru+3 product. Ruthenium isophthalate is a semiconductor having a volume resistivity of about 10 ohm-cm at room temperature. This salt decomposes at 85° C., as compared to 550° C. for the corresponding terephthalate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05162557 |
| 출처 데이터셋 | uspto-grants-1992_11 |
| ORD ID | ord-a0b8de18c018411fb6088db50669b66f |
| 출처 메모 | uspto-grants-1992_11 |