Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
5-(Methoxymethyl)furan-2-carboxylic acid → HCID 18780016, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 5-(Methoxymethyl)furan-2-carboxylic acid | HCID 1125227 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 촉매 | Rhodium | HCID 23948 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | HCID 18780016 | HCID 18780016 | 102.5% |
반응 단계
A solution of 5-methoxymethylfuran-2-carboxylic acid (3.10g) in ethyl acetate (40ml) was hydrogenated over 5% rhodium on carbon (200mg) until hydrogen uptake ceased. The catalyst was filtered off and washed with ethyl acetate. The combined filtrates were evaporated to give the title compound as a colourless oil (3.26g); vmax (film) 1750cm-1 ; δH (CDCl3) 1.75-2.1 (2H,m), 2.1-2.6(2H,m,), 3.45 (3H,s), 3.47 (1H,dd, J 3 and 10 Hz), 3.74 (1H,dd, J 4 and 10Hz), 4.15-4.43 (1H,m) and 4.43-4.63 (1H,m).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06020329 |
| 출처 데이터셋 | uspto-grants-2000_02 |
| ORD ID | ord-dbb2005aa4f24ef994b988d348421e78 |
| 출처 메모 | uspto-grants-2000_02 |