Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Imidazole → HCID 178514066, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Imidazole | HCID 795 | — |
| 반응물 | 4-Aminobiphenyl | HCID 7102 | — |
| 반응물 | 1,1'-Carbonyldiimidazole | HCID 68263 | — |
| 반응물 | HCID 178507487 | HCID 178507487 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | HCID 178514066 | HCID 178514066 | — |
반응 단계
To a solution of N,N-carbonyidiimidazole (0.96 g, 5.0 mmol) and imidazole (0.68 g, 10 mmol) in tetrahydrofuran (10 mL) at 0° C. was added 4-aminobiphenyl (1.0 g, 5.9 mmol) in tetrahydrofuran (10 mL). After stirring at 0 C for 10 min 5-(2-aminophenyl)tetrazole (1.14 g, 7.1 mmol) was added. The reaction was stirred for another 4 hours and filtered. The filtrate was evaporated to dryness and the crude product purified by column chromatography. A yield of 0.28 g was obtained. M.p. 224-226° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06297261B1 |
| 출처 데이터셋 | uspto-grants-2001_10 |
| ORD ID | ord-d1c089ddd3d14f5aa5971d1fa559d6eb |
| 출처 메모 | uspto-grants-2001_10 |