Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methylamine → 10-(Hydroxymethyl)-9-((methylimino)methyl)anthracene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methylamine | HCID 6329 | — |
| 반응물 | 10-(Hydroxymethyl)anthracene-9-carbaldehyde | HCID 3765036 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 10-(Hydroxymethyl)-9-((methylimino)methyl)anthracene | HCID 22662200 | — |
반응 단계
10-(hydroxymethyl)-9-anthraldehyde (3.00 g, 12.7 mmol) was added to 50 mL of a saturated solution of methylamine in methanol and stirred at room temperature for 2 h. The solvent and excess methylamine was removed under reduced pressure to afford the imine as a bright yellow powder (quant); 1H NMR (300.13 MHz, DMSO-d6) δ3.35 (s, 3H), 5.51 (s, 2H), 7.61 (m, 4H), 8.55 (m, 4H), 9.48 (s, 1H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06319540B1 |
| 출처 데이터셋 | uspto-grants-2001_11 |
| ORD ID | ord-8bc12dc99a0047928b869c8fed4a9718 |
| 출처 메모 | uspto-grants-2001_11 |