Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl bromide → 1,3-Butadienylferrocene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl bromide | HCID 7841 | — |
| 반응물 | Ferrocenecarboxyaldehyde | HCID 15184314 | — |
| 반응물 | HCID 178450094 | HCID 178450094 | — |
| 반응물 | HCID 178466060 | HCID 178466060 | — |
| 촉매 | Magnesium | HCID 5462224 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 1,3-Butadienylferrocene | HCID 129665232 | — |
반응 단계
Ferrocenaldehyde or ferrocenyl methyl ketone and allyl bromide are reacted in an ether solvent and in the presence of magnesium metal as a catalyst. The liquid portion of the reaction mixture is introduced into a silica gel column, wherein the weak acidity of the silica gel is able to dehydrate the reaction intermediate 1-ferrocenyl-3-buten-1-ol product. The column is eluted with n-hexane, and after evaporating the solvent from the eluate collected, a purified ferrocenyl-1,3-butadiene product is obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06664409B1 |
| 출처 데이터셋 | uspto-grants-2003_12 |
| ORD ID | ord-1873e47b27344b03a5faf5cb04c75af6 |
| 출처 메모 | uspto-grants-2003_12 |