Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
O-Xylene → TK 12997
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | O-Xylene | HCID 7237 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 1,6-Bis(2,2,6,6-tetramethyl-4-piperidylamino)hexane | HCID 93419 | — |
| 반응물 | s-Triazine, 2-chloro-4,6-bis(diallylamino)- | HCID 95021 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | TK 12997 | HCID 163462 | — |
반응 단계
A mixture of 2,4-bis(diallylamino)-6-chloro-1,3,5-triazine (14.2 grams; 0.046 mole), 4,4'-(hexamethylenediimino)bis(2,2,6,6-tetramethylpiperidine) (9.2 grams; 0.023 mole), powdered sodium hydroxide (1.84 grams; 0.046 mole), and xylene (50 mls) is heated at reflux for 36 hours using a water separator to remove byproduct water. The reaction mixture is then filtered hot and the filtrate is evaporated to obtain a light yellow oil which solidifies on standing. Recrystallization of the solid from hexane gives white needles which on recovery and drying weigh 9.3 grams, mp 119°-120° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04400505 |
| 출처 데이터셋 | uspto-grants-1983_08 |
| ORD ID | ord-5c693575c7224b42a2410b404656f330 |
| 출처 메모 | uspto-grants-1983_08 |