Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Morpholine → N-(1-adamantyl)morpholine-4-carbothioamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Morpholine | HCID 8083 | — |
| 반응물 | Adamantyl isothiocyanate | HCID 107279 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | N-(1-adamantyl)morpholine-4-carbothioamide | HCID 2828003 | — |
반응 단계
The thiourea is prepared by reacting 5.0 g. (0.026 mole) of 1-adamantyl isothiocyanate with 2.5 g. (0.029 mole) of morpholine in 250 ml. of ether for ca. 1 hr. at room temperature. The solid which separates is collected and combined with additional compound from concentration of ether filtrate to a small volume: 6.65 g. (91 percent), m.p. 145-147. The analytical sample is recrystallized from ether, m.p. 148.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04007181 |
| 출처 데이터셋 | uspto-grants-1977_02 |
| ORD ID | ord-6912602631aa45beb0219a09ad070591 |
| 출처 메모 | uspto-grants-1977_02 |