Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Azabicyclo[3.2.2]nonane → 3-{4,6-Bis[(1,1,2,2-tetramethylpropyl)amino]-s-triazin-2-yl}-3-azabicyclo[3.2.2]nonane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Azabicyclo[3.2.2]nonane | HCID 9240 | — |
| 반응물 | 2-Chloro-4,6-di(2,3,3-trimethyl-2-butyl)amino-s-triazine | HCID 15572577 | — |
| 용매 | Diglyme | HCID 8150 | — |
| 생성물 | 3-{4,6-Bis[(1,1,2,2-tetramethylpropyl)amino]-s-triazin-2-yl}-3-azabicyclo[3.2.2]nonane | HCID 9954415 | — |
반응 단계
A 10.25 g. portion of 2-chloro-4,6-bis[(1,1,2,2-tetramethylpropyl)amino]-s-triazine and 7.65 g. of 3-azabicyclo[3.2.2]nonane in 50 ml. of diglyme is heated at reflux for 3 hours and then cooled, giving a pink solid. This solid is collected, washed with diglyme, suspended in 500 ml. of water, stirred, filtered and washed with water giving a pink solid. This solid is recrystallized from ethanol (charcoal being employed in decolorization) to give the desired product m.p. 282°-284° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04261892 |
| 출처 데이터셋 | uspto-grants-1981_04 |
| ORD ID | ord-63c0f65b6203474dad71419269b4f029 |
| 출처 메모 | uspto-grants-1981_04 |