Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Tridecanone → 2-Tridecanone oxime
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Tridecanone | HCID 11622 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Hydroxylamine, N-chloro- | HCID 149953 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Tridecanone oxime | HCID 74054313 | 93% |
반응 단계
A solution of 40 g of methyl undecyl ketone and 18 g of hydroxylamino hydrochloride in 200 ml of ethanol, 60 ml of water and 10 g of NaOH is refluxed for 5 hours and thereafter cooled. The ethanol is distilled off in vacuo and the reaction mixture is then diluted with water, extracted with ether and the ethereal extract is dried over Na2SO4. The ether is distilled off and the solid residue is then distilled in vacuo, affording 40 g of 2-tridecanone oxime. Melting point (after recrystallisation from ether); 51°-53° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04263324 |
| 출처 데이터셋 | uspto-grants-1981_04 |
| ORD ID | ord-4a76a7bc498041f6abcd50afd442ad9a |
| 출처 메모 | uspto-grants-1981_04 |