참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyl but-2-ynoate | HCID 141019 | — |
| 반응물 | 2-(Trimethylsiloxy)-1,3-cyclohexadiene | HCID 4095656 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Methyl 2-methyl-4-trimethylsilyloxybenzoate | HCID 21879730 | 67.1% |
반응 단계
A 50 mL round bottom flask equipped with magnetic stir bar and condenser was charged with 6.0 g of 2-trimethylsilyloxy-1,3-cyclohexadiene, 3.5 g methyl tetrolate in 3 mL dry toluene. The reaction was heated to 150° C. for 50 hours at which point 1H-NMR indicated no starting diene. The raction was concentrated in vacuo to provide 5.7 g (67%) methyl 2-methyl-4-trimethylsilyloxybenzoate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06646010B2 |
|---|
| 출처 데이터셋 | uspto-grants-2003_11 |
|---|
| ORD ID | ord-68b4c341a8d442e9b16cf88834b19ca6 |
|---|
| 출처 메모 | uspto-grants-2003_11 |
|---|
