Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tetramethoxysilane → HCID 178503003, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tetramethoxysilane | HCID 12682 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 반응물 | HCID 178506380 | HCID 178506380 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | HCID 178503003 | HCID 178503003 | 57% |
반응 단계
A Grignard reagent was prepared from 100 ml of THF, magnesium (120 mmole) and 1-trifluoromethoxy-4-(trans-4-(trans-4-chloroethylcyclohexyl)cyclohexyl)benzene (100 mmole) under nitrogen atmosphere. A THF 100 ml solution of tetramethoxysilane (150 mmole) was heated to 65° C., and the Grignard reagent was added dropwise thereto. The solution was stirred at the same temperature for 2 hours, and after left standing for cooling, the reaction mixture was filtered. The solvent was distilled off, and then 1-trifluoromethoxy-4-(trans-4-(trans-4-trimethoxysilylethylcyclohexyl)cyclohexyl)benzene (57 mmole) was obtained by distillation under reduced pressure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06703083B2 |
| 출처 데이터셋 | uspto-grants-2004_03 |
| ORD ID | ord-c5317193ef2e4833bc7f47c236f2fa9b |
| 출처 메모 | uspto-grants-2004_03 |