Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Iodide → Methyl 4-(tetradecyloxy)benzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Iodide | HCID 5238 | — |
| 반응물 | Methylparaben | HCID 7456 | — |
| 반응물 | Myristyl bromide | HCID 8208 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | Methyl 4-(tetradecyloxy)benzoate | HCID 3312490 | 8.1% |
반응 단계
A well stirred mixture of 100 g of methyl 4-hydroxybenzoate, 182.25 g of tetradecylbromide, 136.26 g of potassium carbonate and 4.93 g of sodium iodide in 1-liter of acetone is refluxed for 48 hours. The mixture is poured into ice water, the solid collected and washed with water. The solid is dissolved in chloroform and washed with 1N sodium hydroxide, dried and evaporated to a residue which is crystallized from hexanes to give 18.5 g of the desired product as a white solid, m.p. 64°-66° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05231182 |
| 출처 데이터셋 | uspto-grants-1993_07 |
| ORD ID | ord-a012738f83fa4824a423cb5d3cec533b |
| 출처 메모 | uspto-grants-1993_07 |