Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phenyl Trifluoromethanesulfonate → 2-Triethylsilyl-5-phenyl-4-furaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phenyl Trifluoromethanesulfonate | HCID 548641 | — |
| 반응물 | 3-Furancarboxaldehyde, 5-(triethylsilyl)- | HCID 10878438 | — |
| 반응물 | HCID 178506926 | HCID 178506926 | — |
| 촉매 | Zincchloride | HCID 3007855 | — |
| 촉매 | Tetrakis(triphenylphosphine)palladium | HCID 11979704 | — |
| 생성물 | 2-Triethylsilyl-5-phenyl-4-furaldehyde | HCID 19433144 | — |
반응 단계
Treatment of 2-triethylsilyl-4-furaldehyde with lithio N,N,N'-trimethylethylenediamine, followed by phenyl trifluoromethanesulfonate in the presence of anhydrous zinc chloride and tetrakis (triphenylphosphine) palladium (o) and work up gives the titled aldehyde.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05298633 |
| 출처 데이터셋 | uspto-grants-1994_03 |
| ORD ID | ord-018130448c9e46a38cdbaf860961e47e |
| 출처 메모 | uspto-grants-1994_03 |