Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Iodide → Iodomethyl hexanoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Iodide | HCID 5238 | — |
| 반응물 | Iodomethyl pivalate | HCID 104401 | — |
| 반응물 | Chloromethyl hexanoate | HCID 525229 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | Iodomethyl hexanoate | HCID 12775069 | 78% |
반응 단계
Chloromethyl hexanoate (205 mg, 1.25 mmol) was stirred with sodium iodide (900 mg, 6.0 mmol) in 3 mL of dry acetone for 4 hours at room temperature. Work-up followed the procedure detailed in EXAMPLE 3 above for the preparation of iodomethyl pivalate. Iodomethyl hexanoate, CH3 (CH2)4COOCH2I, was obtained as a yellow oil in 78% yield. NMR values were consistent with the assigned structure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05618803 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-54d37de01bed41b2b2ca412552dad398 |
| 출처 메모 | uspto-grants-1997_04 |