Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrazine hydrate (1:1) → 4-(1-Adamantyl)-3-thiosemicarbazide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrazine hydrate (1:1) | HCID 24654 | — |
| 반응물 | Adamantyl isothiocyanate | HCID 107279 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 4-(1-Adamantyl)-3-thiosemicarbazide | HCID 762709 | 96.1% |
반응 단계
A solution of 1.5 g (0.03 mol) of hydrazine hydrate in 50 ml of EtOH was treated with 3.86 g (0.02 mol) of 1-adamantyl isothiocyanate, and stirred for one hour at room temperature. The product was collected and washed two times with EtOH, affording 4.33 g (96%) of 4-(1-adamantyl)-3-thiosemicarbazide, mp 206°-207° C. This thiosemicarbazide is disclosed in Chemical Abstracts, 70: 11223 (1969); and in U.S. Pat. No. 3,406,180.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04657903 |
| 출처 데이터셋 | uspto-grants-1987_04 |
| ORD ID | ord-c0f15168b1de43af9e2f8e6b6ebdf791 |
| 출처 메모 | uspto-grants-1987_04 |