Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Nitrobenzoyl chloride → Ethyl 2-amino-2-(4-nitrobenzoyloxyimino)acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Nitrobenzoyl chloride | HCID 8502 | — |
| 반응물 | Ethyl 2-amino-2-(hydroxyimino)acetate | HCID 6785548 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Ethyl 2-amino-2-(4-nitrobenzoyloxyimino)acetate | HCID 53689516 | 80.7% |
반응 단계
To a solution of 4-nitrobenzoyl chloride (10 g) in tetrahydrofuran (150 ml) was added a suspension of ethyl 2-amino-2-hydroxyiminoacetate (7.1 g) in tetrahydrofuran (30 ml). After stirring for 2 hours, the precipitates were collected by filtration and washed with diethyl ether to afford ethyl 2-amino-2-(4-nitrobenzoyloxyimino)acetate (12.19 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05622976 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-eb2980772efc4544af937d3ef0d335a3 |
| 출처 메모 | uspto-grants-1997_04 |