Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl Alcohol → Benzyl phenylacetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl Alcohol | HCID 244 | — |
| 반응물 | Phenylacetic Acid | HCID 999 | — |
| 반응물 | Toluene | HCID 1140 | — |
| 반응물 | p-Toluenesulfonic acid | HCID 6101 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Benzyl phenylacetate | HCID 60999 | 83% |
반응 단계
A solution of phenyl acetic acid (27.2 g.), benzyl alcohol (21.6 g.) and p-toluenesulfonic acid (380 mg.) in 100 ml. of toluene was heated under reflux under a Dean-Stark trap until the theoretical (3.6 ml.) quantity of water had been collected. On cooling, the solution was washed with dilute NaHCO3 and saturated NaCl and solvent was removed in vacuo. The resulting oil was distilled at 125°-129° (0.4 torr)1 to give pure benzyl phenylacetate, 37.7 g. (83% yield). ##STR239##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04012383 |
| 출처 데이터셋 | uspto-grants-1977_03 |
| ORD ID | ord-5e7161529e8b4f56b679a458277a4905 |
| 출처 메모 | uspto-grants-1977_03 |