Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dichlorodiphenylsilane → (9-Anthracenyl)diphenylsilanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dichlorodiphenylsilane | HCID 6627 | — |
| 반응물 | 9-Bromoanthracene | HCID 74062 | — |
| 반응물 | Silanol | HCID 142154 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | (9-Anthracenyl)diphenylsilanol | HCID 57572904 | — |
반응 단계
For preparation of the silanol, 20 mmol 9-anthracenyl bromide are metallized with the equimolar amount of n-butyllithium (2 M solution in cyclohexane, 20 mmol) at −20° C. and dichlorodiphenylsilane is then added, in accordance with Example 2.1. When the addition of the dichlorodiphenylsilane has ended, the reaction mixture is heated under reflux for 3 h and then hydrolysed by addition of water (100 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07915457B2 |
| 출처 데이터셋 | uspto-grants-2011_03 |
| ORD ID | ord-194b0c56648d4fe1a9931936334af37c |
| 출처 메모 | uspto-grants-2011_03 |