Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Carbon Tetrachloride → Ethyl 3-bromo-6-methoxy-2-methylbenzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Carbon Tetrachloride | HCID 5943 | — |
| 반응물 | Bromine | HCID 24408 | — |
| 반응물 | 2-Methoxy-6-methyl-benzoic acid ethyl ester | HCID 591060 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Ethyl 3-bromo-6-methoxy-2-methylbenzoate | HCID 11022052 | — |
반응 단계
A mixture of ethyl 6-methyl-2-methoxybenzoate (8.4 g, 43.2 mmol), bromine (6.9 g, 43.2 mmol) and tetrachloromethane (170 ml) is stirred at room temperature for 60 hours. The reaction mixture is poured into water and extracted with ethyl acetate. The organic phase is separated and concentrated. The crude product is obtained as a yellow oil, 10.3 g (87%) and is used without further purification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06001883 |
| 출처 데이터셋 | uspto-grants-1999_12 |
| ORD ID | ord-2f9fb22998714a3b940f3595d535229d |
| 출처 메모 | uspto-grants-1999_12 |