Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Bis(eta-cyclopentadienyl) iron → Mesitylene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| 반응물 | Mesitylene | HCID 7947 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 촉매 | Zirconium chloride (ZrCl4), (T-4)- | HCID 9856075 | — |
| 생성물 | Mesitylene | HCID 7947 | — |
| 생성물 | HCID 178418685 | HCID 178418685 | — |
반응 단계
In accordance with the procedure of Example 4, 10 g (0.043 mol) of ZrCl4 are added at 60° C. under argon over the course of 1 hour and 10 minutes to a stirred mixture of 60 ml of mesitylene, 8 g (0.043 mol) of ferrocene and 5.7 g (0.043 mol) of sublimed AlCl3. Working up is effected as in Example 4, affording 20.1 g (83.4% of theory) of crude (η6 -mesitylene)-η5 -(cyclopentadienyl)-iron(II) tetrapnenylborate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05247107 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-6e509896da094dc58fef5e22f2f94349 |
| 출처 메모 | uspto-grants-1993_09 |