Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → HCID 73197185, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | 2-Methyl-2-nitropropane | HCID 11672 | — |
| 반응물 | 2,4-Dichlorobenzaldehyde | HCID 13404 | — |
| 촉매 | Zinc | HCID 23994 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | HCID 73197185 | HCID 73197185 | — |
반응 단계
To a suspension of 2,4-dichlorobenzaldehyde (462.1 mg, 2.64 mmol), 1,1-dimethylnitroethane (543.1 mg, 5.27 mmol) and zinc (514.8 mg, 7.88 mmol) in ethanol (3.0 ml) was added acetic acid (944.8 mg, 15.7 mmol) dropwise at 5° C. while stirring. The mixture was stirred at room temperature for one day. Zinc acetate was filtered off and the filtrate was concentrated and purified by silica gel chromatography (hexane/ethyl acetate=5/1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06194461B1 |
| 출처 데이터셋 | uspto-grants-2001_02 |
| ORD ID | ord-66e336a05ee1493aaabe778d1c38f8e1 |
| 출처 메모 | uspto-grants-2001_02 |