Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Pyridine → Methyl N-[[[[[(diethoxyphosphinothioyl)methylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Pyridine | HCID 1049 | — |
| 반응물 | Methomyl | HCID 4109 | — |
| 반응물 | Thionyl Chloride | HCID 24386 | — |
| 반응물 | O,O-diethyl methylamidothiophosphate | HCID 759370 | — |
| 생성물 | Methyl N-[[[[[(diethoxyphosphinothioyl)methylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate | HCID 86739072 | — |
반응 단계
Methyl N-[[[[[(diethoxyphosphinothioyl)methylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate was prepared by the procedure employed in Example 9, by reacting methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate (2.43 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole), and O,O-diethyl methylphosphoramidothioate (2.75 g, 0.015 mole) in pyridine (10 ml). Recrystallization from chloroformhexane afforded 2.75 g of colorless prisms of the formula below, mp 78~78.5°. ##STR24##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04410518 |
| 출처 데이터셋 | uspto-grants-1983_10 |
| ORD ID | ord-265b5a901a7441c6a088e0deb982ff31 |
| 출처 메모 | uspto-grants-1983_10 |