Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene → 2-Nitrobenzyl hexadecanesulfonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene | HCID 241 | — |
| 반응물 | 2-Nitrobenzyl alcohol | HCID 11923 | — |
| 반응물 | 1-Hexadecanesulfonyl chloride | HCID 96923 | — |
| 용매 | Triethylamine | HCID 8471 | — |
| 생성물 | 2-Nitrobenzyl hexadecanesulfonate | HCID 15095411 | — |
반응 단계
To a stirred solution of 7.65 g (0.05 mol) of 2-nitrobenzyl alcohol in 75 ml of benzene containing 5.05 g (0.05 mol) of triethylamine was added 16.25 g (0.05 mol of hexadecanesulfonyl chloride. The mixture was stirred an additional four hours. The mixture was evaporated to dryness in vacuo and the solid taken up into a mixture of ether and water. The ether layer was separated and dried over MgSO4. Evaporation of the ether gave a solid which was crystallized from absolute ethanol (yield 14.3 g, m.p. 63°-65° C.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04740600 |
| 출처 데이터셋 | uspto-grants-1988_04 |
| ORD ID | ord-279744f9a4f14cb39654d967c3e65756 |
| 출처 메모 | uspto-grants-1988_04 |