Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethyl Ether → [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 4-Benzyloxybenzyl chloride | HCID 70042 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride | HCID 383834 | — |
반응 단계
4-Benzyloxybenzyl chloride (1 g, 0.0043 mol) and triphenyl phosphine (1.127 g, 1 equivalent) in anhydrous toluene (20 mL) were refluxed under nitrogen for ˜8–10 hours. A white precipitate appeared in the reaction mixture. The reaction mixture was then cooled to room temperature and ether (100 mL) was added. The precipitated phosphonium salt was collected by filtration, rinsed with ether and air dried. Yield=0.55 g (25%). MALDI-TOF MS 459.51 obs. (459.54 calc.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07083986B2 |
| 출처 데이터셋 | uspto-grants-2006_08 |
| ORD ID | ord-10387fc676524c57a88f49116ff26a5c |
| 출처 메모 | uspto-grants-2006_08 |