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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 732287생성일: 2026년 10월 24일

1H-Indole-5-Carboxylic Acid → 6,11-dihydro-5H-diindolo[2,3-a:2',3'-c]carbazole-2,9,14-tricarboxylic acid

https://huagongshe.com/ko/reaction/732287

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참여 물질

역할이름HCID투입량
반응물1H-Indole-5-Carboxylic AcidHCID 74280—
용매Sulfuric acid methanolHCID 18363649—
생성물6,11-dihydro-5H-diindolo[2,3-a:2',3'-c]carbazole-2,9,14-tricarboxylic acidHCID 2324006894.6%

반응 조건

온도25 °C

반응 단계

1.07 g of the indole-5-carboxylic acid trimer synthesized in Example 12 was suspended in 30 ml of 10% aqueous sulfuric acid-methanol solution, and the suspension was agitated for 2 hours at the temperature of 25° C. The suspension was suction-filtered with a perforated funnel, washed with methanol and dried to obtain 1.00 g of 6,11-dihydro-5H-diindolo [2,3-a:2′,3′-c] carbazole-2,9,14-tricarboxylic acid (indole-5-carboxylic acid trimer) with a light green color. The resultant trimer was pressure-molded with a tablet molding machine and the mold was cut into a piece with the diameter of 10 mm and thickness of 1 mm. A conductivity thereof was measured by the four terminal method and found to be 0.55 S/cm. The result of elemental analysis was: <C9.00H4.90N1.09O1.98Cl0.03(SO4)0.12>3.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US07585981B2
출처 데이터셋uspto-grants-2009_09
ORD IDord-b66d97e64f3946f496f6647493e4fd3e
출처 메모uspto-grants-2009_09