Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tributylstannane → Tert-butyl-dimethyl-(4-tributylstannanyl-but-3-enyloxy)-silane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tributylstannane | HCID 5948 | — |
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | (But-3-yn-1-yloxy)(tert-butyl)dimethylsilane | HCID 4304567 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | Tert-butyl-dimethyl-(4-tributylstannanyl-but-3-enyloxy)-silane | HCID 85142049 | 95% |
반응 단계
A solution of Example 31A (1.08 g, 5687 mmol), tri-(n-butyl)tin hydride (1.43 mL, 5.31 mmol), and AIBN (cat.) in benzene (10 mL) was stirred at 80° C. for 3 hours. Volatiles were removed under reduced pressure to provide the title compound as a colorless oil (>95% E-isomer). 1H NMR (300 MHz, CDCl3): δ 0.05 (s, 6H), 0.80-0.98 (m, 15H), 0.90 (s, 9H), 1.23-1.38 (m, 6H), 1.42-1.53 (m, 6H), 2.34-2.40 (m, 2H), 3.66 (d, J=6 Hz, 2H), 5.94-5.98 (m, 2H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08829041B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-25012324cdb343cab96c1dd75ae95dc2 |
| 출처 메모 | uspto-grants-2014_09 |