Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Vinyltrimethylsilane → 5-Bromo-1,3-diethyl-2-vinylbenzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Vinyltrimethylsilane | HCID 79102 | — |
| 반응물 | 4-Bromo-2-methyl-1-vinylbenzene | HCID 22598656 | — |
| 반응물 | 5-Bromo-1,3-diethyl-2-iodobenzene | HCID 44891101 | — |
| 생성물 | 5-Bromo-1,3-diethyl-2-vinylbenzene | HCID 57842909 | 90% |
반응 단계
Using a procedure analogous to that used to prepare 30A, 37A (1.9 g, 5.6 mmol) was reacted with trimethyl(vinyl)silane to yield 37B (1.2 g, 90%) as a red oil. 1H NMR (400 MHz, CDCl3) δ ppm 1.14 (t, J=7.47 Hz, 6 H) 2.60 (q, J=7.62 Hz, 4 H) 5.21 (dd, J=17.80, 1.98 Hz, 1 H) 5.51 (dd, J=11.42, 1.76 Hz, 1 H) 6.64(dd, J=18.02, 11.42 Hz, 1 H) 7.18 (s, 2 H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07592331B2 |
| 출처 데이터셋 | uspto-grants-2009_09 |
| ORD ID | ord-7487c9ce4df64f3f90a1fbe5c23cf1b8 |
| 출처 메모 | uspto-grants-2009_09 |