Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cis-3-azido-6-benzhydryl-tetrahydropyran → Cis-(6-benzhydryl-tetrahydropyran-3-yl)-amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cis-3-azido-6-benzhydryl-tetrahydropyran | HCID 11630718 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Cis-(6-benzhydryl-tetrahydropyran-3-yl)-amine | HCID 11565229 | 78% |
반응 단계
Cis-5-azido-2-diphenylmethyl-tetrahydropyran 14 (0.3 g, 1.02 mmol) in methanol (25 ml) was hydrogenated under the catalyst of 10% Pd—C (0.03 g, 10% wt) for 4 hr (Procedure C) to give cis-5-amino-2-diphenylmethyl-tetrahydropyran 15 (0.21 g, 78%) as an oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08841464B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-71b10c7887a54c0da9c25d008c71bb77 |
| 출처 메모 | uspto-grants-2014_09 |