Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxirane, methylene- → 7-Isojasmonic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxirane, methylene- | HCID 3029326 | — |
| 반응물 | 12-Oxo-phytodienoic acid | HCID 5280411 | — |
| 반응물 | Linoleic Acid | HCID 5280450 | — |
| 반응물 | Linolenic Acid | HCID 5280934 | — |
| 반응물 | (9Z,12Z,15Z)-9,12,15-Octadecatrieneperoxoic acid | HCID 6439905 | — |
| 용매 | Jasmonic Acid | HCID 5281166 | — |
| 생성물 | 7-Isojasmonic acid | HCID 7251183 | — |
반응 단계
The first step in jasmonic acid biosynthesis is the formation of linoleic acid (Chemical Abstracts name: (Z,Z)-9,12-Octadecadienoic acid) and linolenic acid (Chemical Abstracts name: (Z,Z,Z)-9,12,15-Octadecatrienoic acid) from membrane lipid breakdown, catalysed by phospholipase. Linoleic and linolenic acid are converted to 13-hydroperoxylinolenic acid by the action of lipoxygenase. 13-hydroperoxylinolenic acid is converted into 12,13 expoxy-octadecatrienoic acid in the presence of allene oxide synthase (AOS), and then converted into 12-oxo-phytodienoic acid by allene oxide cyclase (AOC). Following reduction and three steps of β-oxidation, (+)-7-iso-jasmonic acid is formed.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07262151B2 |
| 출처 데이터셋 | uspto-grants-2007_08 |
| ORD ID | ord-ffa33f04afc84218be758884d966223e |
| 출처 메모 | uspto-grants-2007_08 |