Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2'-Bromoacetophenone → 2-Bromophenacyl Bromide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2'-Bromoacetophenone | HCID 75060 | — |
| 반응물 | 2-Bromo-1-(2,5-dichlorophenyl)ethanone | HCID 2756907 | — |
| 생성물 | 2-Bromophenacyl Bromide | HCID 2737522 | 57% |
반응 단계
This compound was prepared from 1-(2-bromo-phenyl)-ethanone (2.5 g, 12.6 mmol) in the manner described for 2-bromo-1-(2,5-dichlorophenyl)ethanone (Method I-2), affording 1.98 g (57%) of 2-bromo-1-(2-bromo-phenyl)-ethanone as a clear oil. 1H-NMR (CD2Cl2) δ 8.13 (t, J=2 Hz, 1H), 7.92 (dm, J=8 Hz, 1H), 7.78 (dm, J=8 Hz, 1H), 7.42 (t, J=8 Hz, 1H), 4.49 (s, 2H); TLC Rf=0.38, 15%, ethyl acetate-hexanes.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07144885B2 |
| 출처 데이터셋 | uspto-grants-2006_12 |
| ORD ID | ord-fb732bb161314e53801e944433772152 |
| 출처 메모 | uspto-grants-2006_12 |