Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,4-Benzenediboronic acid → 1,4-Bis(benz[a]anthracen-4-yl)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,4-Benzenediboronic acid | HCID 230478 | — |
| 반응물 | 9-Bromo-10-(naphthalen-2-yl)anthracene | HCID 16116263 | — |
| 생성물 | 1,4-Bis(benz[a]anthracen-4-yl)benzene | HCID 59412541 | — |
반응 단계
Preparation analogous to Example 7. 9-Bromo-10-(2-naphthyl)anthracene is replaced by 4.1 g (25 mmol) of benzene-1,4-diboronic acid. Recrystallisation five times from o-dichlorobenzene (about 20 ml/g); sublimation (p=5×10−5 mbar, T=400° C.). Yield: 11.1 g (21 mmol), 84.0%, purity 99.9% (HPLC).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08986852B2 |
| 출처 데이터셋 | uspto-grants-2015_03 |
| ORD ID | ord-c68f21b4d7884c3fadcfef3873d0d128 |
| 출처 메모 | uspto-grants-2015_03 |