Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Aniline → Methyl 3-(phenylamino)benzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Aniline | HCID 6115 | — |
| 반응물 | Methyl 3-bromobenzoate | HCID 12070 | — |
| 생성물 | Methyl 3-(phenylamino)benzoate | HCID 614856 | — |
반응 단계
Reaction of methyl 3-bromobenzoate with aniline according to general procedure A provided methyl ester of Compound 3 as a yellow oil (94% yield). 1H NMR (CDCl3, 500 MHz): δ=7.73 (s, 1H), 7.56 (d, J=7.6 Hz, 1H), 7.22-7.35 (m, 4H), 7.10 (d, J=8.5 Hz, 2H), 7.00 (t, J=7.4 Hz, 1H), 5.81 (s, 1H), 3.91 (s, 3H). 13C NMR (CDCl3, 125 MHz): δ=167.3, 143.9, 142.6, 131.6, 129.7, 129.6, 122.0, 121.9, 121.7, 118.7, 118.4, 52.3.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09271961B2 |
| 출처 데이터셋 | uspto-grants-2016_03 |
| ORD ID | ord-605c2488ebc24d648db00545c3d7ce2a |
| 출처 메모 | uspto-grants-2016_03 |