참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 2-Ethylcyclohexanone | HCID 20474 | — |
| 반응물 | Hydroxyamine hydrochloride | HCID 443297 | — |
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Ethyl-1-(hydroxyimino)cyclohexane | HCID 574622 | 52% |
반응 단계
To a solution of 2-ethylcyclohexanone (104.3 mmol) in water and ethanol, and sodium acetate (125.1 mmol) were added hydroxylamine hydrochloride (156.4 mmol), the reaction was heated at 70° C. overnight. The ethanol was removed under reduced pressure, and the reaction mixture was dissolved in water. The aqueous layer was extracted with ether, and the combined organic extracts were washed with brine, dried over sodium sulfate, and concentrated to give 2-ethyl-1-(hydroxyimino)cyclohexane (52%) as a thick oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06638927B2 |
|---|
| 출처 데이터셋 | uspto-grants-2003_10 |
|---|
| ORD ID | ord-de37c91fea554c2dbb8c9f037e81cac7 |
|---|
| 출처 메모 | uspto-grants-2003_10 |
|---|
