HRID1605663

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID87715

1-(4-Cyclohexylphenyl)ethan-1-one

C14H18O

$结构：CCOC(=O)/C=C(\C)OCC$

HCID5354173

Ethyl (2E)-3-ethoxy-2-butenoate

C8H14O3

PRODUCTS

生成物

$结构：CC(=O)/C=C(\C)c1ccc(C2CCCCC2)cc1$

HCID68134323

未命名化合物

收率 55%

PROCEDURE

实验过程

(E)-4-(4-cyclohexyl-phenyl)-3-pentene-2-one was prepared analogous to Example 52 from 4'-cyclohexyl-acetophenone and ethyl (E)-3-ethoxy-crotonate with a yield of 55% of theory. B.p. 148°-151°C at 0.4 mm Hg; m.p. 49°-50°C (after recrystallization from methanol and petroleum ether). Characteristic signals in NMR (CDCl3): τ 3.50 (1H-q; /J/=1.2 ± 0.1 Hz); τ 7.50 (3H-d; /J/=1.2 ± 0.1 Hz).

WORKUP

后处理

customm.p. 49°-50°C (after recrystallization from methanol and petroleum ether)