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HRID1613603

反应详情

EQUATION

反应方程式

HRID 1613603 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1ccc2c(c1)C1OC1CCO2
HCID14580522

未命名化合物

结构：CC1CCC(=O)N1[C@@H]1c2cc([N+](=O)[O-])ccc2OCC[C@H]1O[Si](C)(C)C
HCID131717814

未命名化合物

PRODUCTS

生成物

1
结构：CC1CCC(=O)N1[C@@H]1c2cc([N+](=O)[O-])ccc2OCC[C@H]1O
HCID131717813

未命名化合物

PROCEDURE

实验过程

Starting from 10.4 g (50 mmol) of 4,5-epoxy-7-nitro-2,3,4,5-tetrahydro-1-benzoxepin, 6.7 g of trans-7-nitro-5-(5-(R,S)-methyl-2-oxo-pyrrolidin-1-yl)-4-trimethylsilyloxy-2,3,4,5-tetrahydro-1-benzoxepin melting in the range 179°-185° C. are isolated. After elimination of the silyl group and after crystallization and chromatography on silica gel (ethyl acetate/cyclohexane 7:3) the diastereomers A and B are obtained.

WORKUP

后处理

  1. customare isolated
  2. customAfter elimination of the silyl group and after crystallization and chromatography on silica gel (ethyl acetate/cyclohexane 7:3) the diastereomers A and B
  3. customare obtained